烃源岩不同性质有机酸的分离及其检测方法     

杜佳宗  何蓓  蔡进功  雷天柱  刘庆  谢忠怀 《高校地质学报》2020,26(5):540-548

烃源岩中的有机酸来源于有机质，但有机质具有不同的赋存形式，有机酸具有不同性质，这将影响有机酸与不同赋存有机质的关系，进而影响分离和检测方法。文章在总结前人对有机质赋存形式和有机酸性质等特征的基础上，提出烃源岩中的有机酸并以非单一的形式存在，具有水溶性、脂溶性和难溶性有机酸三种类型，游离有机质中存在水溶性和脂溶性有机酸，而结合有机质中存在水溶性、脂溶性和难溶性有机酸。因此在检测方法上需采取分步分离的方法，且根据有机酸的性质选取合适的检测方法，即水溶性有机酸利用离子色谱检测，索氏抽提得到的脂溶性有机酸利用气相色谱—质谱检测，通过酸解抽提残渣得到的难溶性有机酸利用红外光谱检测，全面系统地认识烃源岩中有机酸含量和类型等特征。这对进一步探讨烃源岩各种类型有机酸特征和演化规律，深化烃源岩有机质生烃以及有机—无机相互作用等机理都具有重要意义。  相似文献   

Cretaceous tectonic evolution of the Neo-Tethys in Central Iran:Evidence from petrology and age of the Nain-Ashin ophiolitic basalts     

Tahmineh Pirnia  Emilio Saccani  Ghodrat Torabi  Marco Chiari  Spela Gorican  Edoardo Barbero 《地学前缘(英文版)》2020,11(1):57-81

The Nain and Ashin ophiolites consist of Mesozoic melange units that were emplaced in the Late Cretaceous onto the continental basement of the Central-East Iran microcontinent(CEIM).They largely consist of serpentinized peridotites slices;nonetheless,minor tectonic slices of sheeted dykes and pillow lavas-locally stratigraphically associated with radiolarian cherts-can be found in these ophiolitic melanges.Based on their whole rock geochemistry and mineral chemistry,these rocks can be divided into two geochemical groups.The sheeted dykes and most of the pillow lavas show island arc tholeiitic(IAT)affinity,whereas a few pillow lavas from the Nain ophiolites show calc-alkaline(CA)affinity.Petrogenetic modeling based on trace elements composition indicates that both IAT and CA rocks derived from partial melting of depleted mantle sources that underwent enrichment in subduction-derived components prior to melting.Petrogenetic modeling shows that these components were represented by pure aqueous fluids,or sediment melts,or a combination of both,suggesting that the studied rocks were formed in an arc-forearc tectonic setting.Our new biostratigraphic data indicate this arc-forearc setting was active in the Early Cretaceous.Previous tectonic interpretations suggested that the Nain ophiolites formed,in a Late Cretaceous backarc basin located in the south of the CEIM(the so-called Nain-Baft basin).However,recent studies showed that the CEIM underwent a counter-clockwise rotation in the Cenozoic,which displaced the Nain and Ashin ophiolites in their present day position from an original northeastward location.This evidence combined with our new data and a comparison of the chemical features of volcanic rocks from different ophiolites around the CEIM allow us to suggest that the Nain-Ashin volcanic rocks and dykes were formed in a volcanic arc that developed on the northern margin of the CEIM during the Early Cretaceous in association with the subduction,below the CEIM,of a Neo-Tethys oceanic branch that was existing between the CEIM and the southern margin of Eurasia.As a major conclusion of this paper,a new geodynamic model for the Cretaceous evolution of the CEIM and surrounding Neo-Tethyan oceanic basins is proposed.  相似文献   

硼的地球化学性质及其在俯冲带的循环与成矿初探   总被引：2，自引：1，他引：1  

林秋婷  陈晨  刘海洋 《岩石学报》2020,36(1):5-12

硼是广泛应用于化工、农业、材料科学及核工业领域的重要元素。硼与氢的核聚变反应是未来具备运用潜力的清洁能源。硼作为典型的亲石元素,是高度不相容元素。硼元素容易富集于蚀变洋壳及蛇纹石化地幔橄榄岩中。而在板块俯冲过程中,由于硼具有强的流体活动性,会优先赋存于流体中。因此,当蛇纹石化的大洋岩石圈及覆于其上的沉积物在俯冲过程中发生脱水,这使得弧前地幔楔发生大规模的蛇纹石化。此时大量硼元素很可能随俯冲流体释放并封存于弧前地幔楔中。目前已发现的超大型硼矿床主要位于聚合型板块边缘,尤其土耳其拥有世界上最大的硼酸盐储量。我们推测这些矿床的形成基础条件之一可能与弧前高度蛇纹石化的地幔楔有关。尤其是在洋 陆俯冲环境,弧前蛇纹岩或蛇绿混杂岩首先通过俯冲侵蚀再循环到火山弧岩浆中,使得岩浆更富集硼。随后弧火山喷发大量富硼的火山岩、岩浆热液及水气。在岩浆冷却过程中,硼元素析出、沉淀于火山表面,并伴随风化、侵蚀过程汇聚至碰撞造山带的封闭湖盆之中。此外,干冷的气候条件下也进一步促进了硼的成矿。我国具有形成大型、超大型硼矿的地质条件,应加大研究及探勘力度,并适当购买硼作为战略储备。  相似文献   

Origin and depositional environments of source rocks and crude oils from Niger Delta Basin: Carbon isotopic evidence     

《China Geology》2020,3(4):602-610

Thirty-nine crude oils and twenty-one rock samples from Niger Delta Basin, Nigeria have been characterized based on their isotope compositions by elemental analysis-isotope ratio mass spectrometry and gas chromatography-isotope ratio mass spectrometry. The bulk carbon isotopic values of the whole rock extracts, saturate and aromatic fractions range from –28.7‰ to –26.8‰, –29.2‰ to –27.2 ‰ and –28.5 ‰ to –26.7 ‰, respectively while the bulk carbon isotopic values of the whole oils, saturate and aromatic fractions range from –25.4 ‰ to –27.8 ‰, –25.9 ‰ to –28.4 ‰ and –23.5 ‰ to –26.9 ‰, respectively. The average carbon isotopic compositions of individual alkanes (nC₁₂-nC₃₃) in the rock samples range from –34.9‰ to –28.2‰ whereas the average isotopic values of individual n-alkanes in the oils range from –31.1‰ to –23.8‰. The δ¹³C isotope ratios of pristane and phytane in the rock samples range from –29.2 ‰ to –28.2 ‰ and –30.2 ‰ to –27.4 ‰ respectively while the pristane and phytane isotopic values range from –32.1‰ to –21.9‰ and –30.5‰ to –26.9‰, respectively. The isotopic values recorded for the samples indicated that the crude oils were formed from the mixed input of terrigenous and marine organic matter and deposited under oxic to sub-oxic condition in lacustrine-fluvial/deltaic environments. The stable carbon isotopic compositions were found to be effective in assessing the origin and depositional environments of crude oils in the Niger Delta Basin.  相似文献   

青藏高原凯蒙蛇绿混杂岩中碱性火山岩的发现及意义     

潘政  史仁灯  黄启帅  陈生生  龚小晗  吴钪  杨可 《岩石矿物学杂志》2020,39(1):18-34

班公湖-怒江洋的关闭时间直接制约青藏高原早期构造演化的认识。最近,在班公湖-怒江缝合带南侧凯蒙蛇绿混杂岩中发现一碱性火山岩,岩性主要是橄榄粗安岩,具粗面结构,斑晶主要是更长石和少量普通辉石,基质主要由更长石、普通辉石和少量填隙的碱性长石组成,有的具辉绿结构。岩石化学成分较一致,Si O2含量介于51.34%~53.91%之间,Ti O2含量为1.02%~1.55%,具有高Al2O3(17.06%~18.46%)和Na2O(4.90%~6.36%)、低K2O(0.05%~0.88%)含量特点,大多数Mg#大于60,最高68.62,里特曼指数(σ)介于3.65~4.47之间,为碱性系列火山岩;富集Sr、Rb、Ba等大离子亲石元素,亏损Nb、Y、Yb等高场强元素,相对富集Zr、Ti,Nb/U、Zr/Nb、La/Yb等比值稳定,分别为7.45~8.51、15.92~17.26和7.26~8.06;(87Sr/86Sr)i值变化范围较小,介于0.706~0.707之间,(143Nd/144Nd)t值在0.512 368~0.512 548之间,说明源区较为一致,结合Ce/Pb-Si O2图解判断结果,认为凯蒙碱性火山岩具有原始地幔、陆壳和深海沉积物源区混合特征。锆石U-Pb同位素定年结果表明该火山岩年龄为101.8±1.1 Ma,可能形成于洋壳俯冲阶段末期,由大陆边缘陆壳与俯冲洋壳板片断离导致软流圈地幔上涌诱发部分熔融所致,推测班公湖-怒江洋大约在早白垩世晚期关闭。  相似文献   

Phase equilibrium modelling of the amphibolite to granulite facies transition in metabasic rocks (Ivrea Zone,NW Italy)     

Barbara E. Kunz  Richard W. White 《Journal of Metamorphic Geology》2019,37(7):935-950

The development of thermodynamic models for tonalitic melt and the updated clinopyroxene and amphibole models now allow the use of phase equilibrium modelling to estimate P–T conditions and melt production for anatectic mafic and intermediate rock types at high‐T conditions. The Permian mid‐lower crustal section of the Ivrea Zone preserves a metamorphic field gradient from mid amphibolite facies to granulite facies, and thus records the onset of partial melting in metabasic rocks. Interlayered metabasic and metapelitic rocks allows the direct comparison of P–T estimates and partial melting between both rock types with the same metamorphic evolution. Pseudosections for metabasic compositions calculated in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O (NCKFMASHTO) system are presented and compared with those of metapelitic rocks calculated with consistent end‐member data and a–x models. The results presented in this study show that P–T conditions obtained by phase equilibria modelling of both metabasic and metapelitic rocks give consistent results within uncertainties, allowing integration of results obtained for both rock types. In combination, the calculations for both metabasic and metapelitic rocks allows an updated and more precisely constrained metamorphic field gradient for Val Strona di Omegna to be defined. The new field gradient has a slightly lower dP/dT which is in better agreement with the onset of crustal thinning of the Adriatic margin during the Permian inferred in recent studies.  相似文献   

Single subduction zone for the generation of Devonian ophiolites and high‐P metamorphic belts of the Variscan Orogen (NW Iberia)     

Rubn Díez Fernndez  Ricardo Arenas  Sonia Snchez Martínez  Irene Novo‐Fernndez  Richard Albert 《地学学报》2020,32(4):239-245

Within the Variscan Orogen, Early Devonian and Late Devonian high‐P belts separated by mid‐Devonian ophiolites can be interpreted as having formed in a single subduction zone. Early Devonian convergence nucleated a Laurussia‐dipping subduction zone from an inherited lithospheric neck (peri‐Gondwanan Cambrian back‐arc). Slab‐retreat induced upper plate extension, mantle incursion and lower plate thermal softening, favouring slab‐detachment within the lower plate and diapiric exhumation of deep‐seated rocks through the overlying mantle up to relaminate the upper plate. Upper plate extension produced mid‐Devonian suprasubduction ocean floor spreading (Devonian ophiolites), while further convergence resulted in plate coupling and intraoceanic ophiolite imbrication. Accretion of the remaining Cambrian ocean heralded Late Devonian subduction of inner sections of Gondwana across the same subduction zone and the underthrusting of mainland Gondwana (culmination of NW Iberian allochthonous pile). Oblique convergence favoured lateral plate sliding, and explained the different lateral positions along Gondwana of terranes separated by Palaeozoic ophiolites.  相似文献   

Geochemical characteristics of a pre-Middle Jurassic oceanic crust fragment from the Central Pontides in northern Turkey: Geodynamic implications on intra-oceanic subduction initiation     

《Chemie der Erde / Geochemistry》2020,80(1):125535

The Central Pontides (northern Turkey) is one of the key localities to understand the geodynamic evolution of the Palaeo- and Neotethyan oceans. It consists of the pre-Jurassic basement units, the Early Jurassic and the Early Cretaceous accretionary complexes, the widespread Middle Jurassic continental arc magmatics and the Late Jurassic to Tertiary cover units. The Early Cretaceous accretionary complex is represented by the Central Pontide Structural Complex and includes the Middle Jurassic oceanic units, which were metamorphosed during the Early Cretaceous. Apart from these oceanic units, a few metaophiolite and serpentinite fragments have been recognized within the basement units, which may represent the remnants of an older ocean. The pre-Middle Jurassic Devrekani Metaophiolite is the largest oceanic fragment and tectonically intercalated within/between the Devrekani Metamorphics and the Çangaldağ Metamorphic Complex. It is mainly composed of harzburgites, dunites with chromite veins and metagabbros, and cut by metabasaltic andesites and metadacites. Petrographically, the gabbro consists mainly of plagioclase and clinopyroxene, and displays phaneritic/porphyritic texture. In contrast, the metabasaltic andesite includes plagioclase and mica phenocrysts within a fine-grained groundmass. Also, the metadacite is composed predominantly of quartz, plagioclase, and mica minerals. Two different magmatic groups belonging to completely different tectono-magmatic settings have been geochemically determined based on the immobile trace element systematics. The metadacites and metabasaltic andesites are akin to continental arc magmatics and characterized by negative Nb and Ta anomalies and depleted HFSE relative to Th and La contents. However, the metagabbro samples display the geochemical signatures of boninitic rocks and characterized by highly depletion in HFSEs and REEs relative to N-MORB. The Devrekani Metaophiolite in the Central Pontides may represent another remnant of pre-Middle Jurassic oceanic crust generation and can be north-eastward continuation of the Permian-aged Almacık complex and the Boğazköy Metaophiolite fragment in the western Sakarya Composite Terrane. It may have been cut by intrusions of the extensive Middle Jurassic continental arc magmatism after its imbrication within the basement unit. The presence of pre-Middle Jurassic oceanic units may indicate that the Paleozoic ocean may have survived as the Jurassic Intra-Pontide Ocean between the Scythian Platform and Sakarya Composite Terrane during the Mesozoic time. Thus, the Intra-Pontide Suture may normally include the Palaeozoic and Mesozoic remnants of the long-lived northward subducting Tethyan ocean.  相似文献   

中国火山温泉气体地球化学特征及其在火山监测中的应用     

魏费翔  许建东  上官志冠  潘波 《震灾防御技术》2018,13(4):938-949

中国火山温泉主要分布在吉林长白山、云南腾冲和黑龙江五大连池等火山区。这些火山虽然处于休眠状态，但大面积的温泉分布指示着岩浆房存在的可能性。本文总结了前人研究成果，分析了中国主要火山区温泉气体地球化学特征，并探讨了温泉气体在火山监测中的应用。长白山、腾冲和五大连池火山区温泉气体地球化学性质类似，都以CO₂为主要气体，含量在80%以上，最高可达99%以上，其它气体组分包括CH₄、N₂、O₂、SO₂、H₂S、He和H₂等。长白山火山温泉气体中氦同位素比值（3He/4He）最高，约为4—6R_A，CO₂中碳同位素比值（δ13C）为-7.9‰—-1.3‰，CH₄中碳同位素为-48.0‰—-28.7‰；腾冲火山温泉气体氦同位素比值为3—5.5R_A，CO₂中的碳同位素为-6.49‰—-2.07‰，CH₄中碳同位素为-23.5‰—-9.3‰；五大连池火山温泉气体氦同位素比值约为3R_A，CO₂中的碳同位素比值为-9.6‰—-3.1‰，CH₄中碳同位素为-47.2‰—-44.4‰。3个火山区的温泉气体均显示地幔来源的岩浆气体特征，并在上升运移过程中受地壳或古俯冲物质的影响。  相似文献   

重磁三维反演伊犁盆地中部密度和磁性结构          下载免费PDF全文

索奎  张贵宾  梅岩辉  马勇胜 《地球物理学报》2018,61(8):3410-3419

伊犁盆地中部区域地处多个构造单元的交汇区，构造复杂，缺乏高精度地质资料，制约了对盆地构造演化的进一步认识.本文联合使用多种先验信息作为约束条件，利用高精度重磁数据反演获得了研究区地下海拔-10 km以浅的三维密度和磁性结构，增强了反演结果的可靠性.结果揭示以白石墩次凸为中心发育了一个"北断南超"的南西-北东向不对称型凹陷，北部沉积厚度大于南部；区内主要断裂具有高角度特征，生烃中心受断裂控制，阿吾拉勒山前凹陷浅部可能发育逆掩断裂；火成岩以侵入的基性火成岩为主，伴有部分喷出火成岩和中酸性火成岩.  相似文献